Search results for "Isotope geochemistry"

Orbitally induced limestone/marlstone rhythms in the Albian—Cenomanian Cismon section (Venetian region, northern Italy): Sedimentology, calcareous an…

1996

Abstract A multidisciplinary study of the upper Albian—Cenomanian portion of the Cismon section (Venetian region, northern Italy) was undertaken in order to characterize the cyclic alternations of carbonate-rich and carbonate-poor layers and to investigate their possible origin and cyclic patterns. Limestone semicouplets are characterized by abundant radiolarians and micarbs (micron-sized calcitic fragments), common planktonic foraminifera, strong bioturbation, good oxygenation as expressed by the Mn* and V/(V+Ni) parameters, high Si/Al ratio, low K/Al, in the absence of pyrite and organic matter. The marlstone semicouplets are, on the contrary, frequently laminated, rich in pyrite and orga…

Chemical and isotopic characterization of the gases of Mount Etna (Italy)

1997

Abstract In the period 1990–1995, 43 samples of dissolved gases in groundwaters (wells, springs and drainage galleries) and 64 samples of free gases (fumaroles, bubbling and soil gases) from the Mount Etna area were collected and analysed. Isotopic analyses were also carried out of both the carbon of the CO 2 in free gases and dissolved inorganic carbon (DIC) in the waters. The chemical composition of the gases depends on the relative abundances of three interacting components. These are gases of (1) atmospheric origin enriched in O 2 and N 2 , present almost exclusively in dissolved gases, (2) deep origin enriched in CO 2 , prevalent in the majority of cases, and (3) more superficial origi…

Geochemistry, Isotope Geochemistry and Geochronology: Application to Field Studies

1990

Structural studies make it possible to reconstruct the metamorphic and deformation history of a rock body but do not provide information on the absolute timing of these processes. Likewise, field observations and structural work alone may not unambiguously identify the protoliths of many high-grade gneisses or the compositional changes associated with migmatisation, anatexis and the general action of fluid and/or vapour phases in a rock. Geochemical research can answer many of these problems but, as most of this research is laboratory-oriented, we limit ourselves to some general outlines of the possible lines of research, so that these can be borne in mind during fieldwork.

Geochemistry, geochronology and isotope geology of Nakfa intrusive rocks, northern Eritrea: products of a tectonically thickened Neoproterozoic arc c…

2001

Abstract The north-south-trending Neoproterozoic volcano-sedimentary plutonic associations in northern Eritrea are part of the Nubian Shield. The Nakfa intrusive rocks range in composition from gabbro to syeno-diorite to granite and alkaline syenite and intrude supracrustal rocks of volcanic and sedimentary origin. All granitoid rocks are metaluminous or slightly peraluminous and have typical I-type chemical signatures. The calc-alkaline intrusive rocks and the alkaline syenites have geochemical characteristics (e.g. low Nb values) typical of arc intrusives and plot as volcanic arc granites on various discriminant diagrams. Single zircon evaporation Pb-Pb ages and conventional multigrain U-…

Are oxygen isotope fractionation factors between calcite and water derived from speleothems systematically biased due to prior calcite precipitation …

2021

Abstract The equilibrium oxygen isotope fractionation factor between calcite and water (18αcalcite/H2O) is an important quantity in stable isotope geochemistry and allows in principle to infer temperature variations from carbonate δ18O if carbonate formation occurred in thermodynamic equilibrium. For this reason, many studies intended to determine the value of the oxygen isotope fractionation factor between calcite and water (18αcalcite/H2O) for a wide range of temperatures using modern cave calcite and the corresponding cave drip water or ancient speleothem carbonate and fluid inclusion samples. However, the picture that emerges from all of these studies indicates that speleothem calcite i…

Isotope geochemistry of Pantelleria volcanic fluids, Sicily Channel rift: a mantle volatile end-member for volcanism in southern Europe

2000

Chemical and isotopic ratio (He, C, H and O) analysis of hydrothermal manifestations on Pantelleria island, the southernmost active volcano in Italy, provides us with the first data upon mantle degassing through the Sicily Channel rift zone, south of the African–European collision plate boundary. We find that Pantelleria fluids contain a CO2–He-rich gas component of mantle magmatic derivation which, at shallow depth, variably interacts with a main thermal (∼100°C) aquifer of mixed marine–meteoric water. The measured 3He/4He ratios and δ13C of both the free gases (4.5–7.3 Ra and −5.8 to −4.2‰, respectively) and dissolved helium and carbon in waters (1.0–6.3 Ra and −7.1 to −0.9‰), together wi…

Record of 1.82 Ga Andean-type continental arc magmatism in NE Rajasthan, India: Insights from zircon and Sm–Nd ages, combined with Nd–Sr isotope geoc…

2009

Abstract We document a Palaeoproterozoic Andean-type continental arc granitoid emplacement event in the northwestern segment of the Aravalli mountain range, NW India. Our study is focused on the Jasrapur pluton which is dominated by monzogranites with a subordinate amount of granodiorite and quartz monzodiorite. These rocks carry typical continental arc geochemical signatures, such as high-K calc-alkaline, mildly peraluminous, I-type and magnesian features, as well as high Rb and low Nb, Y and Rb/Zr ratios, decoupling between LILE and HFSE, and negative Nb–Ta and Ti anomalies. Conventional geothermobarometric estimates suggest high temperature (~ 800 °C) and pressure (≥ 600 MPa) conditions …

Dissolution and precipitation of gypsum and carbonate minerals in soils on evaporite deposits, central Sicily: isotope geochemistry and microfabric a…

1993

Abstract Soil profiles developed from carbonate- and sulphate-rich deposits of the Gessoso-Solfifera Formation (Miocene) were sampled in central Sicily (544 mm annual precipitation and a strongly seasonal rainfall regime). Carbon and oxygen isotope data supported by mineralogical and thin section investigations indicate that meteoric waters and groundwaters dissolve and repricipitate carbonates and gypsum in the soil profiles. The boundary between the C horizon and the overlying one is the formation site of 18O depleted carbonates (calcite and/or dolomite) presumably precipitated from percolating waters during wet periods. Greater δ18O values of carbonates in the shallower horizons suggest …

Isotope geochemistry of bulk carbonate from the CRP-3 drillhole, Victoria Land Basin, Antarctica.

2003

The tectonic domains of southern and western Madagascar

2019

Abstract Southern and western Madagascar is comprised of five tectonic provinces that, from northeast to southwest, are defined by the: (i) Ikalamavony, (ii) Anosyen, (iii) Androyen, (iv) Graphite and (v) Vohibory Domains. The Ikalamavony, Graphite and Vohibory Domains all have intermediate and felsic igneous protoliths of tonalite-trondhjemite-granodiorite-granite composition, with positive eNd, and low Sr and Pb isotopic ratios. All three domains are interpreted to be the products of intra-oceanic island arc magmatism. The protoliths of the Ikalamavony and Graphite Domains formed repectively between c. 1080–980 Ma and 1000–920 Ma, whereas those of the Vohibory Domain are younger and date …